Well-dispersed bimetallic nanoparticles confined in mesoporous metal oxides and their optimized catalytic activity for nitrobenzene hydrogenation

被引：116

作者：

Liu, Juanjuan ^{[1
]}

Zou, Shihui ^{[1
]}

Xiao, Liping ^{[1
]}

Fan, Jie ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310003, Zhejiang, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 02期

基金：

美国国家科学基金会;

关键词：

ENHANCED ELECTROCATALYTIC ACTIVITY; OXYGEN REDUCTION; CORE-SHELL; PD; SILICA; ALLOY; CHEMISTRY; CARBON; SIZE; AU;

D O I：

10.1039/c3cy00689a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Well-dispersed bimetallic nanoparticles (BMNPs = PtPd/AuPd/AuPt) confined in mesoporous metal oxides (MMOs = TiO2/Al2O3/SiO2/ZrO2) are synthesized by a general and mild one-step sol-gel strategy. This approach allows facile control over the compositional parameter of the supported BMNPs and the MMOs. Moreover, we can also control the formation of the alloy by simply adjusting the loading content. The catalytic results of PtPd-MMO composites in the hydrogenation of nitrobenzene have shown that the performance is highly composition-dependent and support-dependent with Pt1Pd3-m-SiO2 showing the optimum activity.

引用

页码：441 / 446

页数：6

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