Synthesis and structures of the triple-decker type complexes CpCo(μ-1,3-C3B2Me5)MX2L (M=Rh and Ir; X=Cl and Br; L=Me2SO and PPh3)

被引：0

作者：

Romanov, Alexander S. ^{[1
,2
]}

Muratov, Dmitry V. ^{[1
]}

Antipin, Mikhail Yu ^{[1
,2
]}

Siebert, Walter ^{[3
]}

Kudinov, Alexander R. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 119991, Russia

[2] New Mexico Highlands Univ, Dept Nat Sci, Las Vegas, NM 87701 USA

[3] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2012年 / 715卷

关键词：

Boron; Cobalt; Heterocycles; Rhodium; Iridium; Triple-decker complexes; RHODIUM; LIGANDS; HYDROGENATION;

D O I：

10.1016/j.jorganchem.2012.06.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric triple-decker type halides [CpCo(mu-1,3-C3B2Me5)MX2](2) (M = Rh, X = Cl, 1; M = Ir, X = Cl, 2; M = Rh, X = Br, 3; M = Ir, X = Br, 4) react with Me2SO and PPh3 giving adducts CpCo(mu-1,3-C3B2Me5) M(L) X-2 (5-12). The Me2SO ligand is S-bonded to the metal atom in the solid state, while in acetone it is O-bonded. Structures of 5-12 were confirmed by X-ray diffraction. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：136 / 140

页数：5

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