Epoxidation of electrophilic alkenes in ionic liquids

被引：37
|
作者：
Bortolini, O
Conte, V
Chiappe, C
Fantin, G
Fogagnolo, M
Maietti, S
机构：
[1] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy
[2] Univ Foggia, IPPA Fac Agr, I-71100 Foggia, Italy
[3] Dipartimento Chim Bioorgan & Biofarm, I-56126 Pisa, Italy
来源：
GREEN CHEMISTRY | 2002年 / 4卷 / 02期
关键词：
D O I：
10.1039/b110009m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A fast and efficient procedure is proposed for the epoxidation of electrophilic alkenes, the structures of which resemble the vitamin K class, in ionic liquids as solvents and using aqueous basic Solutions of hydrogen peroxide as oxidant. Yields of epoxides ranging from very good to almost quantitative are observed for all the substrates analysed.
引用
收藏
页码：94 / 96
页数：3
相关论文
共 50 条
  • [41] The first Corey-Chaykovsky epoxidation and cyclopropanation in ionic liquids
    Chandrasekhar, S
    Narasihmulu, C
    Jagadeshwar, V
    Reddy, KV
    TETRAHEDRON LETTERS, 2003, 44 (18) : 3629 - 3630
  • [42] ELECTROPHILIC PERFLUOROALKYLATION OF ALKENES
    UMEMOTO, T
    NAKAYAMA, SI
    JOURNAL OF FLUORINE CHEMISTRY, 1982, 21 (01) : 74 - 74
  • [43] ELECTROPHILIC CARBOXYLATION OF ALKENES
    MAYR, H
    VONDERBRUGGEN, U
    CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (02): : 339 - 345
  • [44] Electrophilic additions to alkenes
    Bertolini, TM
    Tran, PD
    JOURNAL OF CHEMICAL EDUCATION, 2006, 83 (04) : 590 - 591
  • [45] Vanadium-catalyzed epoxidation reaction of cinnamyl alcohol in ionic liquids
    Kazemi, Somayeh
    Martin, Alvaro Baeta
    Sordi, Daniela
    Kroon, Maaike C.
    Peters, Cor J.
    Arends, Isabel W. C. E.
    GREEN PROCESSING AND SYNTHESIS, 2012, 1 (06) : 509 - 516
  • [46] Asymmetric alkene epoxidation by Mn(III)salen catalyst in ionic liquids
    Teixeira, Jorge
    Silva, Ana Rosa
    Branco, Luis C.
    Afonso, Carlos A. M.
    Freire, Cristina
    INORGANICA CHIMICA ACTA, 2010, 363 (13) : 3321 - 3329
  • [47] Epoxidation in ionic liquids: A comparison of rhenium(VII) and molybdenum(VI) catalysts
    Betz, Daniel
    Herrmann, Wolfgang A.
    Kuehn, Fritz E.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (20) : 3320 - 3324
  • [48] Ionic Liquids as Micellar Agents in Perrhenate-catalysed Olefin Epoxidation
    Schaeffer, Johannes
    Alber, Monika
    Korth, Wolfgang
    Cokoja, Mirza
    Jess, Andreas
    CHEMISTRYSELECT, 2017, 2 (35): : 11891 - 11898
  • [49] Kinetics of Epoxidation of Cyclooctene with Ionic Liquids Containing Tungstate as Micellar Catalyst
    Zehner, Bastian
    Korth, Wolfgang
    Schmidt, Fabian
    Cokoja, Mirza
    Jess, Andreas
    CHEMICAL ENGINEERING & TECHNOLOGY, 2021, 44 (12) : 2374 - 2381
  • [50] Epoxidation of Olefins Catalyzed by Polyoxomolybdates Formed in-situ in Ionic Liquids
    Graser, Lilian R.
    Juergens, Sophie
    Wilhelm, Michael E.
    Cokoja, Mirza
    Herrmann, Wolfgang A.
    Kuehn, Fritz E.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (10): : 1138 - 1142
12345