Epoxidation of electrophilic alkenes in ionic liquids

被引:37
|
作者
Bortolini, O
Conte, V
Chiappe, C
Fantin, G
Fogagnolo, M
Maietti, S
机构
[1] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy
[2] Univ Foggia, IPPA Fac Agr, I-71100 Foggia, Italy
[3] Dipartimento Chim Bioorgan & Biofarm, I-56126 Pisa, Italy
关键词
D O I
10.1039/b110009m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A fast and efficient procedure is proposed for the epoxidation of electrophilic alkenes, the structures of which resemble the vitamin K class, in ionic liquids as solvents and using aqueous basic Solutions of hydrogen peroxide as oxidant. Yields of epoxides ranging from very good to almost quantitative are observed for all the substrates analysed.
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页码:94 / 96
页数:3
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