Synthesis of N-phytochlorin-substituted (60)fulleropyrrolidines

被引：17
|
作者：
Efimov, A
Tkatchenko, NV
Vainiotalo, P
Lemmetyinen, H
机构：
[1] Tampere Univ Technol, Inst Mat Chem, FIN-33101 Tampere, Finland
[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2001年 / 5卷 / 12期
基金：
芬兰科学院;
关键词：
pheophorbide; phytochlorin; fullerene; photoinduced electron transfer; donor-acceptor dyad;
D O I：
10.1002/jpp.550
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of new phytochlorin-fullerene dyads was prepared. Synthetic pathway includes attachment of glycine to aldehyde-containing phytochlorins via reductive amination, where 3- and 7-carbonyl-substituted pheophorbides exhibit surprisingly different reactivity. The appropriate conditions of reactions (e.g. solvents and reducing agents) were determined in each case. Copyright (C) 2001 John Wiley Sons, Ltd.
引用
收藏
页码：835 / 838
页数：4
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