A Novel Triphosphoramidite Ligand for Highly Regioselective Linear Hydroformylation of Terminal and Internal Olefins

被引：27
|
作者：
Chen, Caiyou [1 ]
Qiao, Yu [1 ]
Geng, Huiling [2 ]
Zhang, Xumu [1 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
[2] Northwest Agr & Forestry Univ, Yangling 712100, Shaanxi, Peoples R China
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 05期
基金：
美国国家科学基金会;
关键词：
RHODIUM-CATALYZED HYDROFORMYLATION; HOMOGENEOUS CATALYSIS; METAL COORDINATION;
D O I：
10.1021/ol400033k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first triphosphorus ligand has been designed and synthesized for highly regioselective linear hydroformylations. A very high ratio (up to 471, 99.8% linear selectivity) was obtained in the linear hydroformylation of representative terminal and internal olefins. For the range of substrates tested, the regioselectivities achieved utilizing the novel triphosphoramidite ligand were much better than those of the bisphosphoramidite ligand and close to those of the tetraphosphoramidite ligand.
引用
收藏
页码：1048 / 1051
页数：4
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