Synthesis and structural studies of cobalt complexes of tridentate ligands incorporating azo, oxime and carboxylate functions

被引：0

作者：

Ganguly, S ^{[1
]}

Karmakar, S ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1999年 / 38卷 / 04期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tridentate ligands H2ArL ( where Ar = Ph, p-tolyl, a-naphthyl) react with cobalt(II) acetate tetrahydrate, affording the dark green Et4N[Co-III(ArL)(2)] complex. The two quasireversible couples (in the range -0.65 to -1.20 V) in the cyclic voltammogram represent azo reduction. The X-ray structure of Et4N[Co(PhL)(2)] has been determined, revealing the meridional binding of the two ligands affording CiS-CON4O2 geometry.

引用

页码：335 / 338

页数：4

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