Synthesis and structural studies of cobalt complexes of tridentate ligands incorporating azo, oxime and carboxylate functions

被引：0
|
作者：
Ganguly, S [1 ]
Karmakar, S [1 ]
机构：
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1999年 / 38卷 / 04期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The tridentate ligands H2ArL ( where Ar = Ph, p-tolyl, a-naphthyl) react with cobalt(II) acetate tetrahydrate, affording the dark green Et4N[Co-III(ArL)(2)] complex. The two quasireversible couples (in the range -0.65 to -1.20 V) in the cyclic voltammogram represent azo reduction. The X-ray structure of Et4N[Co(PhL)(2)] has been determined, revealing the meridional binding of the two ligands affording CiS-CON4O2 geometry.
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页码：335 / 338
页数：4
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