A bimolecular micelle constructed from amphiphilic pillar[5]arene molecules

被引:37
|
作者
Nishimura, Tomoki [1 ]
Sanada, Yusuke [1 ]
Matsuo, Takuma [1 ]
Okobira, Tadashi [2 ]
Mylonas, Efstratios [3 ]
Yagi, Naoto [3 ]
Sakurai, Kazuo [1 ]
机构
[1] Univ Kitakyushu, Dept Chem & Biochem, Kitakyushu, Fukuoka, Japan
[2] Ariake Natl Coll Technol, Dept Chem Sci & Engn, Omuta, Fukuoka, Japan
[3] Japan Synchrotron Radiat Res Inst JASRI, Sayo, Hyogo, Japan
关键词
SHAPE-PERSISTENT MACROCYCLES; SELF-AGGREGATION; HOST; PREDICTION; PARAMETERS; RECEPTOR;
D O I
10.1039/c3cc41186a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An amphiphilic macrocycle based on pillar[5]arene with polar lysine head groups spontaneously self-assembles into a bimolecular micelle in water. This self-assembled structure was characterized by small angle X-ray scattering (SAXS), field flow fluctuation coupled with multi-angle light scattering (FFF-MALS) and atomic force microscopy (AFM). The self-assembly of amphiphilic pillar[5]arene into dimeric spherical micelles represents a new molecular architecture for micelle formation.
引用
收藏
页码:3052 / 3054
页数:3
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