A bimolecular micelle constructed from amphiphilic pillar[5]arene molecules

被引:37
|
作者
Nishimura, Tomoki [1 ]
Sanada, Yusuke [1 ]
Matsuo, Takuma [1 ]
Okobira, Tadashi [2 ]
Mylonas, Efstratios [3 ]
Yagi, Naoto [3 ]
Sakurai, Kazuo [1 ]
机构
[1] Univ Kitakyushu, Dept Chem & Biochem, Kitakyushu, Fukuoka, Japan
[2] Ariake Natl Coll Technol, Dept Chem Sci & Engn, Omuta, Fukuoka, Japan
[3] Japan Synchrotron Radiat Res Inst JASRI, Sayo, Hyogo, Japan
关键词
SHAPE-PERSISTENT MACROCYCLES; SELF-AGGREGATION; HOST; PREDICTION; PARAMETERS; RECEPTOR;
D O I
10.1039/c3cc41186a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An amphiphilic macrocycle based on pillar[5]arene with polar lysine head groups spontaneously self-assembles into a bimolecular micelle in water. This self-assembled structure was characterized by small angle X-ray scattering (SAXS), field flow fluctuation coupled with multi-angle light scattering (FFF-MALS) and atomic force microscopy (AFM). The self-assembly of amphiphilic pillar[5]arene into dimeric spherical micelles represents a new molecular architecture for micelle formation.
引用
收藏
页码:3052 / 3054
页数:3
相关论文
共 50 条
  • [1] Polypseudorotaxane Constructed from Pillar[5]arene and Viologen Polymer
    Ogoshi, Tomoki
    Nishida, Yoko
    Yamagishi, Tada-aki
    Nakamoto, Yoshiaki
    MACROMOLECULES, 2010, 43 (07) : 3145 - 3147
  • [2] Rapid Self-Healing Supramoleular Gel Constructed from Pillar[5]arene
    Zhang, Qian
    Li, Ke-Qing
    Fan, Lu-Lu
    Li, Na
    Li, Jun
    Guo, Hai-Ming
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2021, 222 (10)
  • [3] Redox-Responsive Amphiphilic Macromolecular [2]Pseudorotaxane Constructed from a Water-Soluble Pillar[5]arene and a Paraquat-Containing Homopolymer
    Chi, Xiaodong
    Yu, Guocan
    Ji, Xiaofan
    Li, Yang
    Tang, Guping
    Huang, Feihe
    ACS MACRO LETTERS, 2015, 4 (09): : 996 - 999
  • [4] Pillar[5]arene-based supramolecular polypseudorotaxanes constructed from quadruple hydrogen bonding
    Hu, Xiao-Yu
    Zhang, Pingyuan
    Wu, Xuan
    Xia, Wei
    Xiao, Tangxin
    Jiang, Juli
    Lin, Chen
    Wang, Leyong
    POLYMER CHEMISTRY, 2012, 3 (11) : 3060 - 3063
  • [5] Performance and selectivity of amphiphilic pillar[5]arene as stationary phase for capillary gas chromatography
    Sun, Tao
    Huang, Qiuchen
    Zhang, Wei
    Chen, Ruonan
    Li, Wei
    Chen, Haipeng
    Hu, Shaoqiang
    Cai, Zhiqiang
    Journal of Chromatography A, 2022, 1671
  • [6] Performance and selectivity of amphiphilic pillar[5]arene as stationary phase for capillary gas chromatography
    Sun, Tao
    Huang, Qiuchen
    Zhang, Wei
    Chen, Ruonan
    Li, Wei
    Chen, Haipeng
    Hu, Shaoqiang
    Cai, Zhiqiang
    JOURNAL OF CHROMATOGRAPHY A, 2022, 1671
  • [7] Langmuir and Langmuir-Blodgett Films from Amphiphilic Pillar[5]arene-Containing [2]Rotaxanes
    Thi Minh Nguyet Trinh
    Nierengarten, Iwona
    Holler, Michel
    Gallani, Jean-Louis
    Nierengarten, Jean-Francois
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (22) : 8019 - 8022
  • [8] From Pillar[n]arene Scaffolds for the Preparation of Nanomaterials to Pillar[5]arene-containing Rotaxanes
    Nierengarten, Iwona
    Deschenaux, Robert
    Nierengarten, Jean-Francois
    CHIMIA, 2016, 70 (1-2) : 61 - 66
  • [9] Ordered nanoassemblies from self-assembly of amphiphilic molecule containing pillar[5]arene and azobenzene groups
    Liu, Peng
    Deng, Yingying
    Lu, Jie
    Gou, Xiaoliang
    Han, Qingqing
    Pei, Yi-Rong
    Jin, Long Yi
    POLYMER INTERNATIONAL, 2024, 73 (05) : 359 - 367
  • [10] Pillar[5]arene-based polymeric architectures constructed by orthogonal supramolecular interactions
    Guan, Yangfan
    Ni, Mengfei
    Hu, Xiaoyu
    Xiao, Tangxin
    Xiong, Shuhan
    Lin, Chen
    Wang, Leyong
    CHEMICAL COMMUNICATIONS, 2012, 48 (68) : 8529 - 8531