Cu2[o-Br-C6H3(CO2)2]2(H2O)2•(DMF)8(H2O)2:: A framework deliberately designed to have the NbO structure type

被引：381
|
作者：
Eddaoudi, M
Kim, J
O'Keeffe, M
Yaghi, OM
机构：
[1] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA
[2] Arizona State Univ, Dept Chem, Tempe, AZ 85287 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 03期
关键词：
D O I：
10.1021/ja017154e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of an NbO-type metal-organic framework was achieved by design: o-Br-BDC (BDC = benzenedicarboxylate) was used to direct the formation of Cu2(CO2)4 paddle wheel units at 90° to each other and thus yield the target network. The compound was formulated as Cu2[o-Br-BDC]2(H2O)2·(DMF)8(H2O)2 (MOF-101) and characterized by single-crystal X-ray diffraction [cubic, space group lm3m (No. 229) with a = 21.607(3) Å, V = 10088(2) Å3, Z = 6], which fully confirmed the presence of the expected structure. Despite having very large apertures and voids, MOF-101 has a noninterpenetrated structure, an intriguing observation that is discussed in the context of dual structures. Copyright © 2002 American Chemical Society.
引用
收藏
页码：376 / 377
页数：2
相关论文
共 50 条
  • [41] Formation of high-dimensional frameworks through counterions:: Structure of [Cr2(Bipy)2-(H2O)2(μ-H2O)2(μ-H2O)2(μ,λ-O2C)-C6H4-2-NH2]•(NO3)3•H2O (vol 3, pg 273, 2003)
    Hernández-Molina, M
    Lorenzo-Luis, PA
    Gili, P
    Ruiz-Pérez, C
    CRYSTAL GROWTH & DESIGN, 2003, 3 (03) : 435 - 435
  • [42] A SAXS study of the pore structure evolution in biochar during gasification in H2O, CO2 and H2O/CO2
    Liu, Yurong
    Paskevicius, Mark
    Sofianos, M. Veronica
    Parkinson, Gordon
    Wang, Shuai
    Li, Chun-Zhu
    FUEL, 2021, 292
  • [43] Synthesis, crystal structures, and properties of [Ca(H2O)2(Dmf@CB[6])(Bdc)] • DMF • 4H2O and [Ca(H2O)3(Dmf@CB[6])]Cl2 • 2H2O
    Kovalenko, E. A.
    Palatkina, M. Yu
    Samsonenko, D. G.
    Fedin, V. P.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (06) : 379 - 385
  • [44] Hydrothermal Synthesis and Crystal Structure of One Rare Earth Substituted Keggin-Type Germanotungstate [Cu(en)2]2[Cu(en)2(H2O)]2H3{[Cu(en)2]2[Na2(H2O)1.75][K(H2O)3][Dy2(H2O)2 (GeW11O39)3]} · 6H2O
    Jing-Ping Wang
    Qing-Xia Yan
    Xiao-Di Du
    Jing-Yang Niu
    Journal of Cluster Science, 2008, 19 : 491 - 498
  • [45] Hydrothermal Synthesis and Crystal Structure of One Rare Earth Substituted Keggin-Type Germanotungstate [Cu(en)2]2[Cu(en)2(H2O)]2H3{[Cu(en)2]2[Na2(H2O)1.75][K(H2O)3][Dy2(H2O)2 (GeW11O39)3]} • 6H2O
    Wang, Jing-Ping
    Yan, Qing-Xia
    Du, Xiao-Di
    Niu, Jing-Yang
    JOURNAL OF CLUSTER SCIENCE, 2008, 19 (03) : 491 - 498
  • [46] Vajdakite (MoO2)2(H2O)2AS3+2O5•H2O
    不详
    CANADIAN MINERALOGIST, 2003, 41 : 1318 - 1318
  • [47] SYNCHROTRON RADIATION MEASUREMENTS OF APPEARANCE POTENTIALS FOR (H2O)2+, (H2O)3+, (H2O)H-2(+) AND (H2O)H-3(+) IN SUPERSONIC JETS
    SHIROMARU, H
    SHINOHARA, H
    WASHIDA, N
    YOO, HS
    KIMURA, K
    CHEMICAL PHYSICS LETTERS, 1987, 141 (1-2) : 7 - 11
  • [48] Synthesis and structure of the first protonated zincoborophosphate:: (H3O)Zn(H2O)2BP2O8•H2O
    Shi, HZ
    Shan, YK
    He, MY
    Liu, YY
    Weng, LH
    CHINESE JOURNAL OF CHEMISTRY, 2003, 21 (09) : 1170 - 1173
  • [49] Formation of high-dimensional frameworks through counterions:: Structure of [Cr2(Bipy)2(H2O)2(μ-H2O)2(μ,λ-O2C)-C6H4-2-NH2]•(NO3)3•H2O
    Hernández-Molina, M
    Lorenzo-Luis, PA
    Gili, P
    Ruiz-Pérez, C
    CRYSTAL GROWTH & DESIGN, 2003, 3 (02) : 273 - 277
  • [50] Synthesis and Structure of the First Protonated Zincoborophosphate: （H3O）Zn（H2O）2BP2O8·H2O
    石恒真
    单永奎
    何鸣元
    刘煜炎
    翁林红
    ChineseJournalofChemistry, 2003, (09) : 1170 - 1173
12345