Influence of casting solvents on microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene

被引：59
|
作者：
Funaki, Y
Kumano, K
Nakao, T
Jinnai, H
Yoshida, H
Kimishima, K
Tsutsumi, K
Hirokawa, Y
Hashimoto, T
机构：
[1] Japan Sci & Technol Corp, ERATO, Hashimoto Polymer Phasing Project, Kyoto 6060805, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
POLYMER | 1999年 / 40卷 / 25期
关键词：
poly(2-vinylpyridine)-block-polyisoprene; casting solvent; microphase-separated structures;
D O I：
10.1016/S0032-3861(99)00112-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Influences of casting solvent on the microphase-separated structures of poly(2-vinylpyridine)-block-polyisoprene films were studied by transmission electron microscopy and small-angle X-ray scattering. The variations of the structures obtained were consequences of vitrification of microdomain structures developed during the solvent casting processes. The various microphase-separated structures were properly understood by considering the Hansen's solubility parameters of the solvent and the copolymer, which quantify the polymer-solvent interactions in the system. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：7147 / 7156
页数：10
相关论文
共 50 条
  • [21] FORCES BETWEEN BLOCK COPOLYMERS OF POLY(2-VINYLPYRIDINE) POLY(TERT-BUTYLSTYRENE) IN VARIOUS SOLVENTS
    ANSARIFAR, MA
    LUCKHAM, PF
    POLYMER COMMUNICATIONS, 1988, 29 (06): : 177 - 180
  • [22] Forces between block copolymers of poly(2-vinylpyridine)/poly(tert-butylstyrene) in various solvents
    Ansarifar, M.A.
    Luckham, P.F.
    Polymer communications Guildford, 1988, 29 (06): : 177 - 180
  • [23] Side chain crystallization in microphase-separated poly(styrene-block-octadecylmethacrylate) copolymers
    Hempel, E
    Budde, H
    Höring, S
    Beiner, M
    THERMOCHIMICA ACTA, 2005, 432 (02) : 254 - 261
  • [24] Onion-type micelles from polystyrene-block-poly(2-vinylpyridine) and poly(2-vinylpyridine)-block-poly(ethylene oxide)
    Talingting, MR
    Munk, P
    Webber, SE
    Tuzar, Z
    MACROMOLECULES, 1999, 32 (05) : 1593 - 1601
  • [25] Morphologies and domain sizes of microphase-separated structures of block and graft copolymers of different types
    Matsushita, Y
    Noda, I
    Torikai, N
    MACROMOLECULAR SYMPOSIA, 1997, 124 : 121 - 133
  • [26] Elasticity of sphere-forming polystyrene-b-polyisoprene-b-poly(2-vinylpyridine)/polystyrene-b-polyisoprene/polyisoprene-b-poly(2-vinylpyridine) blends:: The role of dangling chains
    Takahashi, Yoshiaki
    Akazawa, Yoshihiko
    Takano, Atsushi
    Matsushita, Yushu
    POLYMER JOURNAL, 2006, 38 (06) : 603 - 605
  • [27] Rheological characterization and microphase-separated structure of a poly(ether-block-amide) segmented block copolymer
    Yang, IK
    Tsai, PH
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2005, 43 (18) : 2557 - 2567
  • [28] ELECTROCHEMICAL RESPONSE OF ELECTRODES COATED WITH LYSINE STYRENE BLOCK COPOLYMERS WITH MICROPHASE-SEPARATED STRUCTURES
    TSUCHIDA, E
    NISHIDE, H
    ISHIMARU, N
    MONTGOMERY, DD
    ANSON, FC
    JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (11): : 2898 - 2902
  • [29] Effect of Steric Hindrance on Microphase-separated Structures of Block Copolymers Constructed by Hydrogen Bonding
    Chen, Kai-feng
    Liu, Yun
    Shen, Zhi-hao
    Fan, Xing-he
    Yuan, Xiao-tao
    ACTA POLYMERICA SINICA, 2023, 54 (11): : 1681 - 1696
  • [30] Neutron reflection studies on segment distribution of block chains in lamellar microphase-separated structures
    Torikai, N
    Noda, I
    Karim, A
    Satija, SK
    Han, CC
    Matsushita, Y
    Kawakatsu, T
    MACROMOLECULES, 1997, 30 (10) : 2907 - 2914
12345