Experimental proof of the existence of water clusters in fullerene-like PrF3 nanoparticles

被引:21
|
作者
Alakshin, E. M. [1 ]
Blokhin, D. S. [1 ]
Sabitova, A. M. [1 ]
Klochkov, A. V. [1 ]
Klochkov, V. V. [1 ]
Kono, K. [2 ]
Korableva, S. L. [1 ]
Tagirov, M. S. [1 ,2 ]
机构
[1] Kazan Fed Univ, Inst Phys, Kazan 420008, Russia
[2] RIKEN, Wako, Saitama 3510198, Japan
基金
俄罗斯基础研究基金会;
关键词
Nuclear Magnetic Resonance; Fullerene; Nuclear Magnetic Resonance Spectrum; JETP Letter; High Resolution Transmission Electron Microscope;
D O I
10.1134/S0021364012150027
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Synthesized fullerene-like nanoparticles of the Van Vleck paramagnet PrF3 have been studied by nuclear magnetic resonance cryoporometry. Water clusters have been discovered in the internal cavities of the nanoparticles. The analysis of the experimental data indicates that the cluster radius is 1-2.3 nm. The obtained data agree well with the high-resolution transmission electron microscopy data.
引用
收藏
页码:181 / 183
页数:3
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