The Application of Bismuth-Based Oxides in Organic-Inorganic Hybrid Photovoltaic Devices

被引：30
|
作者：
Liu, Zhike
Yan, Feng [1 ]
机构：
[1] Hong Kong Polytech Univ, Dept Appl Phys, Hong Kong, Hong Kong, Peoples R China
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2012年 / 95卷 / 06期
关键词：
VISIBLE-LIGHT; PHOTOELECTROCHEMICAL PROPERTIES; PHOTOCATALYTIC PROPERTIES; ELECTRONIC-STRUCTURE; SOLAR-CELLS; BIVO4; PERFORMANCE; ENHANCEMENT; TRANSITION; MECHANISM;
D O I：
10.1111/j.1551-2916.2012.05088.x
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Bismuth-based ferroelectric oxide films including BiFeO3, Bi2WO6 and BiVO4 with different band structure are prepared by pulsed laser deposition method and used as n-type semiconductors in photovoltaic devices. The oxide films are combined with p-type organic semiconductor poly(3-hexylthiophene) to form bilayer heterojunctions and their photovoltaic effects are systematically studied. Compared with some other oxide semiconductors, such as ZnO or TiO2, the bismuth-based oxides exhibit wider absorption spectra and can induce higher external quantum efficiency, open circuit voltage, and power conversion efficiency of the hybrid devices, indicating that bismuth-based oxides are promising materials for photovoltaic devices.
引用
收藏
页码：1944 / 1948
页数：5
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