A sectoral approach to GHG emissions reductions in developing countries is proposed as a key component of the post-2012 climate change mitigation framework. In this approach, the ten highest-emitting developing countries in the electricity and other major industrial sectors pledge to meet voluntary, 'no-lose' GHG emissions targets in these sectors. No penalties are incurred for failing to meet a target, but emissions reductions achieved beyond the target level earn emissions reduction credits (ERCs) that can be sold to industrialized nations. Participating developing countries establish initial 'no-lose' emissions targets, based upon their national circumstances, from sector-specific energy-intensity benchmarks that have been developed by independent experts. Industrialized nations then offer incentives for the developing countries to adopt more stringent emissions targets through a 'Technology Finance and Assistance Package', which helps to overcome financial and other barriers to technology transfer and deployment. These sector-specific energy-intensity benchmarks could also serve as a means for establishing national economy-wide targets in developed countries in the post-2012 regime. Preliminary modelling of a hybrid scenario, in which Annex I countries adopt economy-wide absolute GHG emissions targets and high-emitting developing countries adopt 'no-lose' sectoral targets, indicates that such an approach significantly improves the likelihood that atmospheric concentrations of CO2 can be stabilized at 450 ppmv by the end of the century.