RETRACTED: High Activity and Selectivity for Silane Dehydrocoupling by an Iridium Catalyst (Retracted article. See vol. 5, pg. 1736, 2015)

被引：7

作者：

Wetherby, Anthony E. ^{[1
]}

Mucha, Neil T. ^{[1
]}

Waterman, Rory ^{[1
]}

机构：

[1] Univ Vermont, Dept Chem, Burlington, VT 05405 USA

来源：

ACS CATALYSIS | 2012年 / 2卷 / 07期

基金：

美国国家科学基金会;

关键词：

dehydrocoupling; iridium; pincer; silane; polysilane; MOLECULAR-WEIGHT POLYAMINOBORANES; TRANSITION-METAL-COMPLEXES; BOND METATHESIS MECHANISM; ELEMENT-ELEMENT BONDS; MAIN-GROUP ELEMENTS; WILKINSONS CATALYST; TERTIARY SILANES; SI-H; DEHYDROPOLYMERIZATION; DEHYDROGENATION;

D O I：

10.1021/cs300186v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Iridium complexes bearing a bis(phosphinite) pincer ligand are,highly active for the dehydrocoupling of phenylsilane, comparable to other catalysts for this reaction. Interestingly, this catalysis produces primarily a single product, the decasilane ring cyclo-(PhSiH)(10) in what is unusually high selectivity for a single product in silane dehydrocoupling.

引用

页码：1404 / 1407

页数：4

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