The effect of the partial pressure of H2S on the permeation of hydrogen in low carbon pipeline steel

被引：107
|
作者：
Zhou, Chengshuang [1 ]
Zheng, Shuqi [1 ]
Chen, Changfeng [1 ]
Lu, Guiwu [1 ]
机构：
[1] China Univ Petr, Dept Mat Sci & Engn, Beijing 102249, Peoples R China
来源：
CORROSION SCIENCE | 2013年 / 67卷
基金：
中国国家自然科学基金;
关键词：
Carbon steel; Hydrogen permeation; Hydrogen embrittlement; Reactor conditions; Acid corrosion; STAINLESS-STEEL; CORROSION; CRACKING; SULFIDE; EMBRITTLEMENT; DIFFUSION; MEMBRANE; INCLUSIONS; TRANSPORT; ENTRY;
D O I：
10.1016/j.corsci.2012.10.016
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The effect of different partial pressures of H2S (P-H2S) on the hydrogen permeation behaviour of API-X52 pipeline carbon steel was investigated in a high-temperature and high-presure hydrogen permeation device. The results showed that the peak value of the hydrogen permeation curves, the corrosion rates, the susceptibility to hydrogen induced cracking and the amount of diffusible hydrogen significantly increased with increasing P-H2S. Hydrogen permeation rate was affected by both P-H2S and corrosion product films. The dense and incrassated corrosion product films provided significant protective properties and suppressed the production of hydrogen atoms. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：184 / 192
页数：9
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