Enantioselective heterogeneous catalytic production of alpha-amino acids

被引：5
|
作者：
Gomes, M [1 ]
Hernández-Valdés, R
Marques, CESJ
Bastos, ML
Aranda, DAG
Antunes, OAC
机构：
[1] Univ Fed Rio de Janeiro, IQ, BR-21945970 Rio De Janeiro, Brazil
[2] Univ Fed Rio de Janeiro, NPPN, BR-21945970 Rio De Janeiro, Brazil
[3] Univ Estacio Sa, Fac Farm, Dept Quim Organ, BR-20261063 Rio De Janeiro, Brazil
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2005年 / 87卷 / 01期
关键词：
chiral catalysis; cinchona alkaloids; hydrogenation; amine addition;
D O I：
10.1007/s11144-006-0004-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present paper the heterogeneous catalytic preparation of alpha-amino acids by hydrogenation of the dehydroamino acids catalyzed by palladium is described. Enantiomeric excess of up to 26% was achieved when the hydrogenation was carried out in ethanol at 0.5 MPa, 298 K with substrate concentration kept at 80 mmol L-1, 50 mol% cinchonidine as modified and triethylamine as additive.
引用
收藏
页码：19 / 24
页数：6
相关论文
共 50 条
12345