Synthesis and Crystal Structure of 4,4′,6,6′-Tetrachloro-2,2′-[(1,4-butylene)dioxybis(nitrilmethylidyne)]diphenol

被引：1
|
作者：
Wang, Li [1 ]
Dong, Xiu-Yan [1 ]
Zhao, Li [1 ]
Yang, Yu-Hua [1 ]
机构：
[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 06期
关键词：
Salen-type bisoxime compound; Synthesis; Crystal structure; Supramolecular interaction; COMPLEXES;
D O I：
10.14233/ajchem.2013.13920A
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The compound 4,4',6,6'-tetrachloro-2,2'-[(1,4-bytylene)dioxybis(nitrilmethylidyne)]diphenol with the molecular formula C18H16Cl4N2O4, was synthesized by the reaction of 3,5-dichloro-2-hydroxybenzaldehyde with 1,4-bis(aminooxy)butane in ethanol. The molecule is disposed about a crystallographic centre of symmetry and the molecule adopts an extended conformation where the two phenoldoxime moieties are aparat from each other. There are strong O-H center dot center dot center dot N intramolecular hydrogen bond and weak C-H center dot center dot center dot O and C-H center dot center dot center dot Cl intermolecular hydrogen bonds and strong intermolecular stacking interactions (the nearest benzene rings are parallel to that of another molecule are ca 2.512(2) angstrom, stabilizing the two dimensional structures of the present compound.
引用
收藏
页码：3440 / 3442
页数：3
相关论文
共 50 条
  • [41] 4,4′-Diamino-2,2′,6,6′-tetramethylbiphenyl
    Batsanov, Andrei S.
    Low, Paul J.
    Paterson, Michael A. J.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O2973 - O2975
  • [42] THE ELECTROCHEMISTRY OF 2,2',4,4',6,6'-HEXANITROAZOBENZENE IN ACETONITRILE
    FIRSICH, DW
    WOOD, RL
    JOURNAL OF CHEMICAL RESEARCH-S, 1993, (04): : 158 - 159
  • [43] THERMOLYSIS OF NITROARENES - 2,2',4,4',6,6'-HEXANITROSTILBENE
    MINIER, LM
    OXLEY, JC
    THERMOCHIMICA ACTA, 1990, 166 : 241 - 249
  • [44] STRUCTURE OF 4,4',6,6'-TETRANITRO-2,2'-DICARBOXYBIPHENYL DIMETHYL ESTER
    POPOVA, EG
    CHETKINA, LA
    SOBOLEV, AN
    JOURNAL OF STRUCTURAL CHEMISTRY, 1991, 32 (03) : 431 - 433
  • [45] 4,4′,6,6′-Tetra-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenol acetone solvate
    Eltayeb, Naser Eltaher
    Teoh, Siang Guan
    Chantrapromma, Suchada
    Fun, Hoong-Kun
    Adnan, Rohana
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O576 - U1000
  • [46] CRYSTAL-STRUCTURE OF 4,4',5,5'-TETRACHLORO-2,2'-BI-1,3-DIOXOLANE
    HUANG, HH
    OGATA, K
    SAKAI, SI
    SIM, KY
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (08) : 2450 - 2451
  • [47] Synthesis, crystal structure and infrared spectra of Cu(II) and Co(II) complexes with 4,4′-dichloro-2,2′-[ethylene dioxybis(nitrilomethylidyne)]diphenol
    Dong, Wenkui
    Shi, Junyan
    Xu, Li
    Zhong, Jinkui
    Duan, Jingui
    Zhang, Yanping
    APPLIED ORGANOMETALLIC CHEMISTRY, 2008, 22 (02) : 89 - 96
  • [48] 4,4′,6,6′-Tetramethyl-2,2′-(butane-1,4diyldithio)dipyrimidine
    Wang, Min
    Cheng, Le-Hua
    Wang, An-Ming
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O3296 - U4247
  • [49] 4,4′,6,6′-Tetramethyl-2,2′-bipyrimidine hexahydrate
    Ma, Yanni
    Zhou, Le
    Deng, Dongsheng
    Ji, Baoming
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O848 - U2806
  • [50] On the configuration of 4,4',6,6'-tetraphenyl-2,2'-dithiopyrylene
    QIAN Ren-Yuan ZHU Dao-Ben Institute of Chemistry
    Chinese Journal of Chemistry, 1987, (04) : 318 - 321
12345