Dissociative photoionization of ferrocene in the Fe:3p inner-valence region

被引:4
|
作者
Tamenori, Y
Boo, BH
Koyano, I [1 ]
机构
[1] Himeji Inst Technol, Dept Mat Sci, Kamigori 6781297, Japan
[2] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea
关键词
ferrocene; dissociative photoionization; Fe : 3p inner-valence excitation; photoion-photoion coincidence measurement;
D O I
10.1016/S0368-2048(98)00440-X
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Dissociative photoionization of ferrocene [Fe(Cp)(2)] has been investigated in the Fe:3p inner-valence region by use of the TOF mass spectrometry and photoion-photoion coincidence technique. The partial ion yields of Fe(Cp)(+), Cp+ and Fe(Cp); show a small enhancement in the Fe:3p --> e(1g) resonance excitation region, while that of doubly charged parent ion [Fe(Cp)(2)(2+)] exhibits a more pronounced enhancement in the vicinity of the Fe:3p ionization threshold. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:87 / 91
页数:5
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