Homochiral porous metal-organic frameworks containing only achiral building blocks for enantioselective separation

被引：53

作者：

Zhang, Hai-Xia ^{[1
]}

Wang, Fei ^{[1
]}

Tan, Yan-Xi ^{[1
]}

Kang, Yao ^{[1
]}

Zhang, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 32期

关键词：

SINGLE-CRYSTAL TRANSFORMATIONS; COORDINATION POLYMER; REVERSIBLE ADSORPTION; NANOPOROUS MATERIALS; HYDROGEN; CRYSTALLIZATION; INDUCTION; CATALYSIS; ZEOLITE; STORAGE;

D O I：

10.1039/c2jm33269h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Enantioselective separation of racemic 1-phenethanol via hydrogen bonding interactions is realized in two enantiomorphous robust metal-organic frameworks (MOFs) with permanent porosity for high hydrogen uptake and reversible guest exchange function through a single-crystal-to-single-crystal fashion, which opens a new route toward enantioselective separation by employing low-cost homochiral MOFs containing only achiral building blocks.

引用

页码：16288 / 16292

页数：5

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