Two Manganese(II) Supramolecular Complexes Based on Imidazole Dicarboxylates: Syntheses, Crystal Structures, and Properties

被引：3
|
作者：
Li, Jie [1 ]
Guo, Beibei [1 ]
Liu, Shaofeng [1 ]
Li, Gang [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2014年 / 44卷 / 07期
基金：
中国国家自然科学基金;
关键词：
property; Mn(II); crystal structure; synthesis; supramolecule; GAS-ADSORPTION; CONSTRUCTION; MOFS; SERIES; ZN;
D O I：
10.1080/15533174.2013.797463
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel Mn(II) complexes [Mn(MDPhH2IDC)(2)(H2O)(2)] (n) (1) (MDPhH3IDC = 2-(3,4-methylenedioxyphenyl)-1H-imidazole-4, 5-dicarboxylic acid), [Mn( m-CPhH3IDC)(2)(H2O)(2)] (n) (2) (m-CPh H4IDC = 2-(3-carboxylphenyl)-1H-imidazole-4,5-dicarboxylic acid) have been hydrothermally synthesized with two kinds of imidazole dicarboxylate ligands, respectively, and structurally characterized by elemental analyses, IR spectra, as well as single crystal X-ray diffraction analysis. The 3D solid-state supramolecular structures of the complexes involve intermolecular hydrogen bonds. Furthermore, the thermal and photoluminescent properties of the complexes have been investigated.
引用
收藏
页码：1041 / 1049
页数：9
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