Na+[Me3NB12Cl11]-•SO2: a rare example of a sodium-SO2 complex

被引：2

作者：

Jenne, Carsten ^{[1
]}

van Lessen, Valentin ^{[1
]}

机构：

[1] Berg Univ Wuppertal, Fak Math & Naturwissensch, Anorgan Chem, D-42119 Wuppertal, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2019年 / 75卷

关键词：

boron cluster; crystal structure; sodium; sulfur dioxide; weakly coordinating anion; DER-WAALS RADII; CRYSTAL-STRUCTURES; COORDINATION; SO2; B12F122; ANION;

D O I：

10.1107/S2056989019004663

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, Na+[Me3NB12Cl11](-)center dot SO2 [systematic name: sodium 1-(trimethylammonio)undecachloro-c/oso-dodecaborate sulfur dioxide], the SO2 molecule is eta(1)-O-coordinated to the Na+ cation. Surprisingly, the SO2 molecule is more weakly bound to sodium than is found in other sodium-SO2 complexes and the SO2 molecule is essentially undistorted compared to the structure of free SO2. The Na+ cation has a coordination number of eight in a distorted twofold-capped trigonal prism and makes contacts to three individual boron cluster anions, resulting in an overall three-dimensional network. Although the number of known eta(1)-O-coordinated SO2 complexes is growing, sodium-SO2 complexes are still rare.

引用

页码：607 / +

页数：18

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