Quantitative kinetic investigation on transmetalation of ArZnX in a Pd-catalysed oxidative coupling

被引：15
|
作者：
Li, Jing [1 ]
Jin, Liqun [1 ]
Liu, Chao [1 ]
Lei, Aiwen [1 ,2 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 83期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
STILLE REACTION; TRIPLE ROLE; MECHANISM; INSIGHTS; STEP; PATHWAYS; IONS;
D O I：
10.1039/c3cc44894k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transmetalation is the rate-limiting step. [R-Pd-Ar] was suggested to be the resting species from the kinetic studies. Quantitative measurement of the transmetalation of ArZnCl with [R-Pd-Ar] from a live Pd-catalysed oxidative coupling reaction was conducted and the corresponding activation enthalpy was determined as 12.3 kcal mol(-1).
引用
收藏
页码：9615 / 9617
页数：3
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