Carbon-Sulfur Bond Formation via Metal-Catalyzed Allylations of Sulfur Nucleophiles

被引：50

作者：

Liu, Wei ^{[1
]}

Zhao, Xiaoming ^{[1
]}

机构：

[1] Tongji Univ, Dept Chem, State Key Lab Pollut Control & Resource Reuse, Shanghai 200092, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2013年 / 45卷 / 15期

关键词：

carbon-sulfur bond formation; sulfur nucleophiles; metal catalysts; allylic substitutions; enantioselective allylations; allylic sulfides; allylic selenides; PALLADIUM-MEDIATED ALLYLATION; ASYMMETRIC ALLYLIC SUBSTITUTIONS; SULFINATE SULFONE REARRANGEMENTS; ALKYL PHENYL SELENIDES; KINETIC RESOLUTION; HOMOGENEOUS CATALYSIS; DIPHENYL DISELENIDE; ENANTIOSELECTIVE SYNTHESIS; CLAISEN REARRANGEMENTS; C-C;

D O I：

10.1055/s-0033-1339176

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The development of practical approaches for the construction of carbon-sulfur bonds is of interest to scientists. In particular, carbon-sulfur bond formation by transition-metal-catalyzed allylations has been attracting great attention. Allylic sulfides are important substances owing to their broad applications in synthetic and pharmaceutical areas. The alkene and sulfur moieties in allylic sulfides can lead to numerous transformations. This review details the development of carbon-sulfur bond formation through palladium-catalyzed rearrangements, palladium-catalyzed allylations, iridium-catalyzed regio- and enantioselective allylations and miscellaneous metal-catalyzed allylic substitutions. Carbon-selenium bond formations via metal-catalyzed allylic substitutions are also reviewed.

引用

页码：2051 / 2069

页数：19

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