Organic facies variability and paleoenvironmental changes on the Moroccan Atlantic coast across the Cenomanian-Turonian Oceanic Anoxic Event (OAE2)

The Cenomanian-Turonian boundary is marked by worldwide paleoenvironmental and paleoceanographical changes that are associated with a perturbation of the global carbon cycle and black shale deposition, called the Oceanic Anoxic Event 2 (OAE2). The objective of this study is to precisely characterize the nature of the organic matter, its variability, paleoenvironmental significance and the preservation conditions of two areas located along the northwest African Shelf where large-scale organic carbon burial contributed significantly to the global carbon burial associated with OAE2. With these premises, an organic petrographic and geochemical approach to the Cenomanian-Turonian record of the Moroccan Atlantic coast allowed the definition of the variability of the organic facies and the paleoenvironmental characterization of the upper Cenomanian-lower Turonian sediments of the Agadir section (Agadir Basin) and of the lower Turonian record of the Amma Fatma section (Tarfaya Basin). At Agadir, the marine microplankton dominated assemblages, with variable degree of amorphization, allowed the characterization of a transgressive-regressive cycle during the upper Cenomanian followed, during the lower Turonian, by a drowning event with establishment of a deep platform environment (under reducing conditions, increase in EFU, EFV, EFMo). The base of the succession (base of W. archaeocretacea biozone) and the top of the upper Cenomanian are characterized by two sea-level lowstands, and a high energy oxic environment, that culminate in emersion surfaces (high EFMn and low organic matter preservation). The organic facies in the lower Turonian of Amma Fatma is largely dominated by bacterial material (probably derived from sulfur bacteria), indicating an outer shelf setting, with some degree of restriction, under euxinic conditions (high EFMo) and high primary productivity (high EFCu, EFNi, EFZn). Differences in terms of the redox conditions between the two basins during the lower Turonian were determined, with anoxia prevailing at Agadir, while euxinic conditions are established at Tarfaya. These are explained by different oceanic circulation patterns, with the mixing of Tethyan waters at Agadir. High primary productivity is recorded at both locations, possibly promoted by the occurrence of upwelling currents. This study further corroborates a delay in the anoxia in Agadir, that during the isotopic excursion of OAE2 only reaches slight dysoxia (upper Cenomanian), and the maintenance of reducing conditions in Tarfaya post-OAE2.