Synthesis and Spectral-Fluorescent Properties of Halogen-Substituted Sn(IV)-Tetraphenylporphyrins

被引：7

作者：

Chizhova, Natalya, V ^{[1
]}

Mamardashvili, Galina M. ^{[1
]}

Dmitrieva, Olga A. ^{[1
]}

Mamardashvili, Nugzar Zh ^{[1
]}

Koifman, Oskar, I ^{[1
]}

机构：

[1] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo 153045, Russia

来源：

MACROHETEROCYCLES | 2019年 / 12卷 / 04期

关键词：

Halogen-substituted porphyrins; Sn(IV)-poiphyrins; complexation and metal exchange reactions; spectral-fluorescent properties; CADMIUM(II);

D O I：

10.6060/mhc190556m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By the reactions of Sn(II) chloride with halogen-substituted porphyrins and their cadmium complexes a synthesis and spectral-fluorescent properties investigation of Sn(IV)-5,10,1,15,20-tetra(4-bromophenyl)porphyrin, Sn(IV)-5,10,15,20-tetra(4-chlorophenyl)porphyrin and Sn(IV)-5,10,15,20-tetra(2,6-dichlorophenyl)porphyrin were carried out The compounds obtained were identified by UV-Vis, IR, H-1 NMR spectroscopy and mass spectrometry. The effect of the meso- and beta-pyrrole substitution on fluorescence quantum yields of the synthesized compounds is estimated.

引用

页码：364 / 369

页数：6

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