Nanosized sulfated zirconia as solid acid catalyst for the synthesis of 2-substituted benzimidazoles

被引:6
|
作者
Abdollahi-Alibeik, Mohammad [1 ]
Hajihakimi, Mohammad [2 ]
机构
[1] Yazd Univ, Dept Chem, Yazd 89195741, Iran
[2] Payame Noor Univ, Dept Chem, Tehran, Iran
来源
CHEMICAL PAPERS | 2013年 / 67卷 / 05期
关键词
sulfated zirconia; nanoparticle; solid acid; catalyst; benzimidazole; reusability; EFFICIENT SYNTHESIS; REUSABLE CATALYST; SELECTIVE SYNTHESIS; BENZOXAZOLES; 1,5-BENZODIAZEPINES; NANOPARTICLES; IODINE;
D O I
10.2478/s11696-013-0311-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The condensation reaction of o-phenylenediamine and arylaldehydes was investigated in the presence of nanosized sulfated zirconia (SO (4) (2-) -ZrO2) as the solid acid catalyst. Nanosized SO (4) (2-) -ZrO2 was prepared and characterized by the XRD, FT-IR, and SEM techniques. The results confirm good stabilization of the tetragonal phase of zirconia in the presence of sulfate. Reusability experiments showed partial deactivation of the catalyst after each run; good reusability can be achieved after calcinations of the recovered catalyst before its reuse.
引用
收藏
页码:490 / 496
页数:7
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