Interaction of a naphthalene based fluorescent probe with Al3+: experimental and computational studies

被引:25
|
作者
Das, Sudipta [1 ]
Karak, Debasis [1 ]
Lohar, Sisir [1 ]
Banerjee, Arnab [1 ]
Sahana, Animesh [1 ]
Das, Debasis [1 ]
机构
[1] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India
关键词
ALUMINUM TOXICITY; MANNICH-BASES; FLUOROMETRIC-DETERMINATION; BIOLOGICAL-ACTIVITY; SCHIFF; DERIVATIVES; ANTIBACTERIAL; CHEMOSENSOR; COMPLEXES; COUMARIN;
D O I
10.1039/c2ay25825k
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The synthesis, characterization and selective interaction of a naphthalene based fluorescent probe (L) with Al3+ is described. The detection limit of L for Al3+ is 4.8 x 10(-7) M. L can efficiently detect Al3+ in living cells under a fluorescence microscope. Experimentally observed structural and spectroscopic features of L and its Al3+ complex have been substantiated by computational calculations using density functional theory.
引用
收藏
页码:3620 / 3624
页数:5
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