A C2 molecule entrapped in the pentagonal-dodecahedral Y2 cage in Y2C2@C82(III)

被引：29
|
作者：
Nishibori, E [1 ]
Narioka, S
Takata, M
Sakata, M
Inoue, T
Shinohara, H
机构：
[1] Nagoya Univ, Dept Appl Phys, Nagoya, Aichi 4648603, Japan
[2] Japan Synchrotron Radiat Res Inst, CREST, JST, Mikazuki, Hyogo 6795198, Japan
[3] Nagoya Univ, Dept Chem, CREST, JST, Nagoya, Aichi 4648602, Japan
[4] Nagoya Univ, Inst Adv Res, CREST, JST, Nagoya, Aichi 4648602, Japan
来源：
CHEMPHYSCHEM | 2006年 / 7卷 / 02期
关键词：
fullerenes; structure elucidation; X-ray diffraction; yttrium;
D O I：
10.1002/cphc.200500437
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Carbon-encapsulating metallofullerenes: A C2 molecule is entrapped in the pentagonal-dodecahedral charge density of Y2 in Y2C2@C82(III) according to the maximum entropy/Rietveld analysis of the synchrotron X-ray powder diffraction data, which clearly show an additional charge-density peak for C2 (blue) inside the pentagonal-dodecahedral Y2 cage (red) in Y 2C2@C82(III) (picture, left) but not in Y 2@C82(III) (right). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：345 / 348
页数：4
相关论文
共 50 条
  • [21] MAPPING AND FUNCTIONAL ANALYSIS OF Y AND C2 MUTANTS
    BRACHET, P
    THOMAS, R
    MUTATION RESEARCH, 1969, 7 (02): : 257 - &
  • [22] PRIMITIVE CARBONATES IN Y82042 (C2)
    BRANDSTATTER, F
    KURAT, G
    GRAHAM, AL
    METEORITICS, 1987, 22 (04): : 336 - 337
  • [23] 方程x2+bx+c=y2的整数解
    周月英
    李振亮
    中等数学, 1994, (06) : 17 - 18
  • [24] Photoelectron spectra of thulium atoms encapsulated C82 fullerene, Tm2@C82 (III) and Tm2C2@C82 (III)
    Miyazaki, Takafumi
    Tokumoto, Youji
    Sumii, Ryohei
    Yagi, Hajime
    Izumi, Noriko
    Shinohara, Hisanori
    Hino, Shojun
    CHEMICAL PHYSICS, 2014, 431 : 47 - 50
  • [25] INFINITE CHAINS OF Y2(H2O)10[C6(COO)6] IN Y2[C6(COO)6].14H2O
    ROBL, C
    HENTSCHEL, S
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1992, 47 (11): : 1561 - 1564
  • [26] A temperature-responsive C2 wagging vibration in Sc2C2@Cs-C82
    Wu, Bo
    Wang, Taishan
    Zhang, Zhuxia
    Jiang, Li
    Wang, Chunru
    CHEMICAL COMMUNICATIONS, 2018, 54 (07) : 775 - 777
  • [27] UPPER BOUNDS FOR THE NUMBER OF SOLUTIONS FOR THE DIOPHANTINE EQUATION y2 = px(Ax2 - C) (C=2, ±1, ±4)
    Bencherif, Farid
    Boumahdi, Rachid
    Garici, Tarek
    Schedler, Zak
    COLLOQUIUM MATHEMATICUM, 2020, 159 (02) : 243 - 257
  • [28] Bonding and structure of Y3C2 and Y3C+2
    Yang, DS
    Zgierski, MZ
    Hackett, PA
    JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (09): : 3591 - 3597
  • [29] A new linelist for the C2 molecule
    Wahlin, R
    Plez, B
    Proceedings of the 13th Cambridge Workshop on Cool Stars, Stellar Systems and the Sun - Proceedings, Vols 1 and 2, 2005, 560 : 1013 - 1015
  • [30] DISSOCIATION OF C2 MOLECULE BY ROTATION
    MESSERLE, G
    KRAUSS, L
    ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1967, A 22 (12): : 2023 - &
12345