Interface magnetic coupling of Fe-phthalocyanine layers on a ferromagnetic surface

被引：37
|
作者：
Annese, E. [1 ,2 ,3 ]
Casolari, F. [1 ,2 ]
Fujii, J. [2 ]
Rossi, G. [2 ,4 ]
机构：
[1] Univ Modena & Reggio Emilia, Dipartimento Fis, I-41100 Modena, Italy
[2] IOM CNR, TASC Lab, I-34149 Trieste, Italy
[3] Elettra Synchrotron SCpA Trieste, I-34149 Trieste, Italy
[4] Univ Milan, Dipartimento Fis, I-20133 Milan, Italy
来源：
PHYSICAL REVIEW B | 2013年 / 87卷 / 05期
关键词：
RAY CIRCULAR-DICHROISM; ELECTRONIC-STRUCTURE; SPIN INJECTION; THIN-FILMS; ANISOTROPY; SPINTRONICS; SUBSTRATE; REVERSAL; STATES; PROBE;
D O I：
10.1103/PhysRevB.87.054420
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Fe-phthalocyanine (FePc) molecules bonded to metal surfaces form rehybridized interface states involving the Fe central atom reflected in changes of orbital and spin configuration. X-ray absorption spectroscopy and x-ray magnetic circular dichroism show the ferromagnetic coupling of the FePc molecules that are in contact with the Co(001) surface, even at room temperature (300 K), while the overgrown parallel layers of FePc in thicker molecular films are decoupled from the interface. The magnetized interface molecular layer reproduces the magnetic structures of the substrate (domains, patterns). DOI: 10.1103/PhysRevB.87.054420
引用
收藏
页数：6
相关论文
共 50 条
  • [31] Fe-Phthalocyanine on Cu(111) and Ag(111): A DFT+vdWs investigation
    Jabrane, Meysoun
    ElHafidi, Mohamed
    El Hafidi, Moulay Youssef
    Kara, Abdelkader
    SURFACE SCIENCE, 2022, 716
  • [32] ELECTROREDUCTION OF NITROGEN TO AMMONIA ON GAS-DIFFUSION ELECTRODES MODIFIED BY FE-PHTHALOCYANINE
    FURUYA, N
    YOSHIBA, H
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 263 (01): : 171 - 174
  • [33] Control of perpendicular magnetic anisotropy at the Fe/MgO interface by phthalocyanine insertion
    Sakamoto, Shoya
    Jackson, Edward
    Kawabe, Takeshi
    Tsukahara, Takuya
    Kotani, Yoshinori
    Toyoki, Kentaro
    Minamitani, Emi
    Miura, Yoshio
    Nakamura, Tetsuya
    Hirohata, Atsufumi
    Miwa, Shinji
    PHYSICAL REVIEW B, 2022, 105 (18)
  • [34] Metallic-like conduction in Co-phthalocyanine/Fe-phthalocyanine composite films grown on sapphire substrates
    Kumar, Arvind
    Singh, Ajay
    Samanta, S.
    Debnath, A. K.
    Aswal, D. K.
    Gupta, S. K.
    APPLIED PHYSICS LETTERS, 2011, 99 (11)
  • [35] Reduced graphene oxide/Fe-phthalocyanine nanosphere cathodes for lithium-ion batteries
    He, Dongxu
    Xue, Weidong
    Zhao, Rui
    Hu, Wencheng
    Marsden, Alexander J.
    Bissett, Mark A.
    JOURNAL OF MATERIALS SCIENCE, 2018, 53 (12) : 9170 - 9179
  • [36] One-step synthesis of Fe-phthalocyanine/Fe3O4 hybrid microspheres
    Meng, Fanbin
    Zhao, Rui
    Zhan, Yingqing
    Lei, Yajie
    Zhong, Jiachun
    Liu, Xiaobo
    MATERIALS LETTERS, 2011, 65 (02) : 264 - 267
  • [37] AMORPHOUS LAYERS AND SURFACE MAGNETIC DOMAINS IN CRYSTALLINE FERROMAGNETIC MATERIALS
    TEJEDOR, M
    GARCIA, JA
    CARRIZO, J
    HERNANDO, B
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1993, 12 (12) : 918 - 919
  • [38] Coverage-Driven Electronic Decoupling of Fe-Phthalocyanine from a Ag(111) Substrate
    Gopakumar, T. G.
    Brumme, T.
    Kroeger, J.
    Toher, C.
    Cuniberti, G.
    Berndt, R.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (24): : 12173 - 12179
  • [39] Magnetic-coupling at the Mn/Fe(001) interface
    Roth, C
    Kleeman, T
    Hillebrecht, FU
    Kisker, E
    PHYSICAL REVIEW B, 1995, 52 (22): : 15691 - 15694
  • [40] Magnetic coupling across a ferromagnetic-metal-alkali-metal interface
    Payson, JS
    Brauer, RE
    Dunifer, GL
    PHYSICAL REVIEW B, 1996, 53 (05): : 2504 - 2516
12345