P/RS intergrowth type phases in the Ln2O3-MO-Al2O3 systems

被引：5

作者：

Tugova, E. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Ioffe Physicotech Inst, Ul Politekhnicheskaya 26, St Petersburg 194021, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 11期

关键词：

P/RS intergrowth type phases; phase formation; geometry stability; search for novel compounds; HETEROVALENT ISOMORPHISM; INTERATOMIC INTERACTIONS; CATION DISTRIBUTION; COMPLEX OXIDES; PEROVSKITE; CRYSTALS; ND; LA; LN;

D O I：

10.1134/S1070363216110025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Regularities of formation of complex aluminates with structure of P/RS intergrowth type phases in the Ln(2)O(3)-MO-Al2O3 systems (Ln = rare-earth element, M = Mg, Ca, Sr, Ba) have been considered. Systematization of the data on formation of complex compounds coexisting with one-layer phases in the Ln(2)O(3)-MO-Al2O3 systems and analysis of geometry criteria of LnMAlO(4) stability is a promising approach to prediction of novel compounds with structure of Ruddlesden-Popper phase.

引用

页码：2410 / 2417

页数：8

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