Alumina-supported Mn(III) and Fe(III) complexes of tridentate Schiff base ligand having ONO-donor sites: Syntheses, characterization and olefin epoxidation study

被引：0

作者：

Adhikary, Jaydeep ^{[1
]}

Banerjee, Priyabrata ^{[2
]}

Chattopadhyay, Tanmay ^{[3
]}

机构：

[1] Univ Calcutta, Dept Chem, Kolkata 700009, India

[2] CSIR, CMERI, Dept Surface Engn & Tribol, Durgapur 713209, India

[3] Panchakot Mahavidyalaya, Dept Chem, Purulia 723121, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2015年 / 54卷 / 10期

关键词：

Catalysts; Supported catalysts; Alumina; Epoxidation; Schiff bases; Manganese; Iron; TERT-BUTYLHYDROPEROXIDE; HYDROGEN-PEROXIDE; CATALYTIC-ACTIVITY; OXIDATION; CYCLOHEXENE; NI(II); CU(II); CO(II); ALKENES; HYDRODESULFURIZATION;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new mononuclear Schiff base complexes, [MLCl(H2O)(2)] [M = Mn(III) or Fe(III); H2L = 2-phenoliminomethylphenol], have been prepared and characterized by elemental analysis, thermogravimetric analysis, UV-vis and FT-IR spectroscopy, cyclic voltammetry and ESI-MS analyses. Both complexes show excellent alkenes epoxidation activity and thus these complexes have been infused over neutral active alumina to prepare the heterogeneous catalysts. These catalysts are characterized by solid UV-vis and FT-IR spectroscopy, thermogravimetric and powder XRD and FE-SEM studies. Finally, the catalysts have been studied for the epoxidation of different types of olefins in presence of terminal oxidants (PhIO and t-BHP) and are easily recyclable.

引用

页码：1175 / 1182

页数：8

共 50 条

[41] Synthesis, characterization, and antibacterial activities of Cr(III), Co(III), Ni(II), and Mn(III) complexes of heptadentate Schiff base ligand derived from tris(2-aminoethyl)amine
Matin, S. J.
Khojasteh, R. R.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (07) : 1763 - 1767
[42] Synthesis, characterization, and antibacterial activities of Cr(III), Co(III), Ni(II), and Mn(III) complexes of heptadentate Schiff base ligand derived from tris(2-aminoethyl)amine
S. J. Matin
R. R. Khojasteh
Russian Journal of General Chemistry, 2015, 85 : 1763 - 1767
[43] Schiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styrene
Demetgul, Cahit
Delikanli, Anil
Saribiyik, Oguz Yunus
Karakaplan, Muruvvet
Serin, Selahattin
DESIGNED MONOMERS AND POLYMERS, 2012, 15 (01) : 75 - 91
[44] Synthesis and characterization of some thiocyanato complexes of Ni(II), Cu(II), Pd(II), Pt(II), Au(III), Ti(III), and V(IV) containing a tridentate Schiff base ligand
Islam, MS
Farooque, MA
Bodruddoza, MAK
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2002, 32 (10): : 1811 - 1823
[45] Syntheses and X-ray Structures of Mixed-Ligand Salicylaldehyde Complexes of Mn(III), Fe(III), and Cu(II) Ions: Reactivity of the Mn(III) Complex toward Primary Monoamines and Catalytic Epoxidation of Olefins by the Cu(II) Complex
Inorg Chem, 3 (323):
[46] Syntheses and X-ray structures of mixed-ligand salicylaldehyde complexes of Mn(III), Fe(III), and Cu(II) ions: Reactivity of the Mn(III) complex toward primary monoamines and catalytic epoxidation of olefins by the Cu(II) complex
Das, G
Shukla, R
Mandal, S
Singh, R
Bharadwaj, PK
vanHall, J
Whitmire, KH
INORGANIC CHEMISTRY, 1997, 36 (03) : 323 - 329
[47] Syntheses, structures, and properties of two mononuclear cobalt(III) azido complexes containing a tetradentate N-donor Schiff base as end-capping ligand
Khan, Sumitava
Roy, Subhasis
Bhar, Kishalay
Mitra, Partha
Slawin, Alexandra M. Z.
Ghosh, Barindra Kumar
TRANSITION METAL CHEMISTRY, 2011, 36 (01) : 99 - 106
[48] Syntheses, structures, and properties of two mononuclear cobalt(III) azido complexes containing a tetradentate N-donor Schiff base as end-capping ligand
Sumitava Khan
Subhasis Roy
Kishalay Bhar
Partha Mitra
Alexandra M. Z. Slawin
Barindra Kumar Ghosh
Transition Metal Chemistry, 2011, 36 : 99 - 106
[49] Synthesis, spectroscopic characterization and catalytic oxidation properties of ONO/ONS donor Schiff base ruthenium(III) complexes containing PPh3/AsPh3
Priyarega, S.
Tamizh, M. Muthu
Karvembu, R.
Prabhakaran, R.
Natarajan, K.
JOURNAL OF CHEMICAL SCIENCES, 2011, 123 (03) : 319 - 325
[50] Co(II), Ni(II), Cu(II) and Zn(II) complexes of tridentate ONO donor Schiff base ligand: Synthesis, characterization, thermal, non-isothermal kinetics and DFT calculations
Kusmariya, Brajendra S.
Mishra, A. P.
JOURNAL OF MOLECULAR STRUCTURE, 2017, 1130 : 727 - 738

← 1 2 3 4 5 →