Preparation and synthetic transformation of alkenyl carbamates into vinyl zirconocene derivatives

被引：12
|
作者：
Chechik-Lankin, H [1 ]
Marek, I [1 ]
机构：
[1] Technion Israel Inst Technol, List Meitner Minerva Ctr Computat Quantum Chem, Inst Catalysis Sci & Technol, Dept Chem,Mallat Family Lab Organ Chem, IL-32000 Haifa, Israel
来源：
SYNTHESIS-STUTTGART | 2005年 / 19期
关键词：
alkynyl carbamates; vinyl zirconocene derivatives; organocopper reagents;
D O I：
10.1055/s-2005-918436
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The carbocupration reaction of alkynyl carbamates leads to the stereospecific preparation of polysubstituted alkenyl carbamates. Subsequent treatment of these enol carbamates with the Negishi reagent gave the corresponding vinyl zirconocene species.
引用
收藏
页码：3311 / 3318
页数：8
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