Synthesis and characterization of novel oligomers from the reaction of bismaleimides with diols

被引：5
|
作者：
Hulubei, C [1 ]
Cozan, V [1 ]
机构：
[1] Inst Macromol Chem, Iasi 6600, Romania
来源：
HIGH PERFORMANCE POLYMERS | 2004年 / 16卷 / 01期
关键词：
bismaleimides; polyaminobismaleimides; Michael addition polymerization; thermal behavior;
D O I：
10.1177/0954008304039410
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
New thermostable oligomers have been obtained by Michael-type reaction between ordinary aliphatic or aromatic glycols and N,N'-4,4'-dibenzylbismaleimide. The polymerization occurred in solution, through hydrogen-transfer addition of the OH group to the unsaturation between the carbonyl groups of the bismaleimide. The structures were characterized by elemental analysis, infrared (IR) and proton nuclear magnetic resonance (H-1-NMR) spectroscopy and thermogravimetric analysis. The mechanical properties and also the resistance to chemical agents was investigated.
引用
收藏
页码：149 / 158
页数：10
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