Transition Metal Frustrated Lewis Pairs

被引：132

作者：

Flynn, Stephanie R. ^{[1
]}

Wass, Duncan F. ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol, Avon, England

来源：

ACS CATALYSIS | 2013年 / 3卷 / 11期

关键词：

frustrated Lewis pairs; cooperative effects; ligand-assisted reactions; small molecule activation; ASYMMETRIC TRANSFER HYDROGENATION; STEREOSELECTIVE HYDROGENATION; HETEROLYTIC CLEAVAGE; ELECTRONIC CONTROL; CARBON-MONOXIDE; BORANE ADDUCTS; IRON COMPLEX; ACTIVATION; REACTIVITY; CO2;

D O I：

10.1021/cs400754w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Frustrated Lewis pair chemistry, in which solution phase combinations of Lewis acid Lewis base pairs (FLPs) act cooperatively to activate small molecules, is one of the most exciting recent developments in main group chemistry. Far less developed but of growing interest are FLP systems containing transition metals as one of the Lewis acid/base components. This Perspective reviews recent developments in this area and makes connections to existing research into cooperative and ligand assisted catalysis.

引用

页码：2574 / 2581

页数：8

共 50 条

[41] Enantioselective Metal-Free Hydrogenation Catalyzed by Chiral Frustrated Lewis Pairs
Shi, Lei
Zhou, Yong-Gui
CHEMCATCHEM, 2015, 7 (01) : 54 - 56
[42] Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs
Moemming, Cornelia M.
Otten, Edwin
Kehr, Gerald
Froehlich, Roland
Grimme, Stefan
Stephan, Douglas W.
Erker, Gerhard
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (36) : 6643 - 6646
[43] Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs
Stephan, Douglas W.
Greenberg, Sharonna
Graham, Todd W.
Chase, Preston
Hastie, Jeff J.
Geier, Stephen J.
Farrell, Jeffrey M.
Brown, Christopher C.
Heiden, Zachariah M.
Welch, Gregory C.
Ullrich, Matthias
INORGANIC CHEMISTRY, 2011, 50 (24) : 12338 - 12348
[44] Computational Study of Metal Free Alcohol Dehydrogenation Employing Frustrated Lewis Pairs
Mane, Manoj V.
Rizvi, Masood A.
Vanka, Kumar
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (04): : 2081 - 2091
[45] Metal-free asymmetric hydrogenation and hydrosilylation catalyzed by frustrated Lewis pairs
Feng, Xiangqing
Du, Haifeng
TETRAHEDRON LETTERS, 2014, 55 (51) : 6959 - 6964
[46] Frustrated Lewis Pairs Catalyzed Asymmetric Metal-Free Hydrogenations and Hydrosilylations
Meng, Wei
Feng, Xiangqing
Du, Haifeng
ACCOUNTS OF CHEMICAL RESEARCH, 2018, 51 (01) : 191 - 201
[47] Phosphine-boranes and related frustrated Lewis pairs: Chelating approach to metal® Lewis acid interaction
Bourissou, D.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[48] Computational Studies of Lewis Acidity and Basicity in Frustrated Lewis Pairs
Gilbert, Thomas M.
FRUSTRATED LEWIS PAIRS I: UNCOVERING AND UNDERSTANDING, 2013, 332 : 267 - 289
[49] Frustrated Lewis pairs as ligands for organometallic catalysis
Nichols, Brian R.
Popp, Brian V.
Bennett, C. Eugene
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[50] Nothing frustrating about "Frustrated Lewis pairs"
Stephan, Douglas W.
DALTON TRANSACTIONS, 2012, 41 (30) : 9015 - 9015

← 1 2 3 4 5 →