Light triggered addition/annulation of 2-isocyanobiphenyls toward 6-trifluoromethyl-phenanthridines under photocatalyst-free conditions

被引：25
|
作者：
Tang, Xiangyang [1 ]
Song, Shuang [1 ]
Liu, Cuibo [1 ,2 ]
Zhu, Rongjiao [1 ]
Zhang, Bin [1 ,2 ,3 ]
机构：
[1] Tianjin Univ, Sch Sci, Dept Chem, Tianjin 300072, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
[3] Tianjin Univ, Minist Educ, Key Lab Syst Bioengn, Tianjin 300072, Peoples R China
来源：
RSC ADVANCES | 2015年 / 5卷 / 93期
基金：
中国国家自然科学基金;
关键词：
SILVER-MEDIATED TRIFLUOROMETHYLATION; C BOND FORMATION; OXIDATIVE CYCLIZATION; METAL-FREE; RADICAL TRIFLUOROMETHYLATION; PHENANTHRIDINE DERIVATIVES; PHOTOREDOX CATALYSIS; EFFICIENT SYNTHESIS; ARYL ISONITRILES; ALKENES;
D O I：
10.1039/c5ra16645d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A photocatalyst-free, light promoted sequential radical addition/annulation of 2-isocyanobiphenyls to 6-trifluoromethyl phenanthridines is presented. Wide substrate scopes and scale-up experiment demonstrate the promising efficiency and utility of this strategy.
引用
收藏
页码：76363 / 76367
页数：5
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