Influence of sintering temperature on screen printed Cu2ZnSnS4 (CZTS) films

被引:34
|
作者
Wang, Yu [1 ]
Huang, Yanhua [1 ]
Lee, Alex Y. S. [2 ]
Wang, Chiou Fu [2 ]
Gong, Hao [1 ]
机构
[1] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 119260, Singapore
[2] DuPont Apollo Ltd, Pak Shek Kok, Hong Kong, Peoples R China
关键词
Cu2SnZnS4; Solar cell; Screen printing; Photosensitivity; EFFICIENCY SOLAR-CELL; THIN-FILMS; LOW-COST; OPTICAL-PROPERTIES; SPRAY-PYROLYSIS; STANNITE; NANOCRYSTALS;
D O I
10.1016/j.jallcom.2012.06.069
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Screen printing is a useful and simple method for coating layers of several solar materials, but care must be taken in preparing stoichiometric CZTS film due to its instability at a high processing temperature and a small chemical potential domain. This paper reports screen printing prepared CZTS films and the influence of sintering temperature on CZTS properties. The thermostability, structural, electronic and optical properties are studied. The direct optical band gap energies of the films vary from 1.39 to 1.60 eV, while the resistivities change from 830 to 6 Omega cm after sintering at different temperatures up to 550 degrees C. A high photosensitivity of 14% is achieved for the sample sintered at 450 degrees C. The phenomena observed are also discussed. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:237 / 241
页数:5
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