Synthesis, structural and NLO properties of the novel copper(I) p-toluenesulfonate π-complex with 1-allyloxybenzotriazole

被引：13

作者：

Slyvka, Yu. ^{[1
]}

Fedorchuk, A. A. ^{[1
]}

Goreshnik, E. ^{[2
]}

Lakshminarayana, G. ^{[3
]}

Kityk, I. V. ^{[4
]}

Czaja, P. ^{[4
]}

Mys'kiv, M. ^{[1
]}

机构：

[1] Ivan Franko Natl Univ Lviv, Dept Inorgan Chem, Kyryla & Mefodiya Str 6, UA-79005 Lvov, Ukraine

[2] Jozef Stefan Inst, Dept Inorgan Chem & Technol, Jamova 39, SI-1000 Ljubljana, Slovenia

[3] Univ Putra Malaysia, Fac Engn, Wireless & Photon Networks Res Ctr, Serdang 43400, Selangor, Malaysia

[4] Czestochowa Tech Univ, Fac Elect Engn, Inst Optoelect & Measuring Syst, 17 Armii Krajowej Str, PL-42200 Czestochowa, Poland

来源：

CHEMICAL PHYSICS LETTERS | 2018年 / 694卷

关键词：

Copper(I); pi-complex; 1,2,3-triazole derivatives; Crystal structure; ac-electrochemical technique; NONLINEAR-OPTICAL PROPERTIES;

D O I：

10.1016/j.cplett.2018.01.041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using the alternating-current electrochemical technique, a novel pi-complex [Cu-2(Alobtr)(2)(H2O)(2)] (CH3C6H4SO3)(2) (1) was obtained starting from copper(II) p-toluenesulfonate and the 1-allyloxybenzotriazole (Alobtr) ethanol solution. The structure 1 should be considered as the first known example of Cu-I(p-CH3C6H4SO3) pi-coordination compound. Alobtr molecule acts as a chelate pi, sigma-ligand (being attached to the Cu(I) by means of allylic C=C bond and the two triazole N atoms) and forms centrosymmetric [Cu-2(Alobtr)(2)(H2O)(2)](2+) dimers. Cationic fragments and pTsO anions are connected by means of (Ow)H center dot center dot center dot O hydrogen bonds into 1D chains. Laser stimulated third harmonic generation for fundamental wavelength 1540 nm is explored. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：112 / 119

页数：8

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