Change in the magnetic properties of [FeII(phen)3](PF6)2 in the solid state by combining grinding and annealing

被引：9

作者：

Ohshita, T ^{[1
]}

Tsukamoto, A ^{[1
]}

Senna, M ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan

来源：

PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2004年 / 201卷 / 04期

关键词：

D O I：

10.1002/pssa.200306757

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

By grinding crystalline [Fe-II(phen)(3)](PF6)(2), the effective magnetic moment, or chi(M)T, increased with simultaneous amorphization. Subsequent annealing further increased chi(M)T, despite the restoration of the crystallinity. This was explained by the recovery of the counterion, PF6-, from its strained state in the intact crystal to a less strained state towards higher spherical symmetry. The effects of annealing preceded by grinding suggest a novel method to control the magnetic states of coordination compounds without regard to their crystalline states.

引用

页码：762 / 768

页数：7

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