Hybrid inorganic-organometallic compounds with gallium-gallium bonds

被引：27
|
作者：
Cowley, AH
Decken, A
Olazabal, CA
机构：
[1] Department of Chemistry, University of New Brunswick, Fredericton
[2] Dept. of Chemistry and Biochemistry, University of Texas at Austin, Austin
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 524卷 / 1-2期
关键词：
gallium; digallium compounds; X-ray crystal structures;
D O I：
10.1016/S0022-328X(96)06382-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first examples of digallium compounds that feature both organo and halo substituents, [Li(THF)(4)][Ar'(Cl)GaGaCl3] (1) and Ar'(Cl)GaGa(Cl)Ar' (2), have been prepared by reaction of Ga2Cl4 . 2 dioxane with LiAr' (Ar' = 2,4,6 -(1)Bu(3)C(6)H(2)). The Ga2Cl2 skeleton of 2 is planar with a dihedral angle of 180 degrees.
引用
收藏
页码：271 / 273
页数：3
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