A Schiff-Based Colorimetric Fluorescent Sensor with the Potential for Detection of Fluoride Ions

被引:17
|
作者
Huang, Cheng-Yin [1 ]
Wan, Chin-Feng [2 ]
Chir, Jiun-Ly [1 ]
Wu, An-Tai [1 ]
机构
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
[2] Chung Shan Med Univ, Sch Appl Chem, Taichung 40201, Taiwan
关键词
Schiff base; Fluorescence; Turn-on; NAKED-EYE DETECTION; SELECTIVE FLUORESCENT; CHEMOSENSOR; ANION; WATER; UREA; RECOGNITION; RECEPTORS; BEARING;
D O I
10.1007/s10895-013-1257-z
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A simple Schiff-based colorimetric fluorescent receptor 1 was prepared. It exhibits a "turn-on-type" mode with high sensitivity in the presence of F-. The change in color is very easily observed by the naked eye in the presence of F-, whereas other anions do not induce such a change. Job plot indicated a 1:2 complexation stoichiometry between receptor 1 and F-. The association constant for 1-F- in CH3CN was determined as 1.32*10(5) M-2 by a Hill plot.
引用
收藏
页码:1107 / 1111
页数:5
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