A New One-Pot Procedure for a Ring Contraction Reaction using Iodine/H2O2

被引：19
|
作者：
Ferreira, Sabrina B. [2 ]
Kaiser, Carlos R. [2 ]
Ferreira, Vitor F. [1 ]
机构：
[1] Univ Fed Fluminense, Dept Quim Organ, Inst Quim, BR-24020141 Rio De Janeiro, Brazil
[2] Univ Fed Rio de Janeiro, Ilha Fundao, LABRMN, Inst Quim, BR-21949900 Rio De Janeiro, Brazil
来源：
SYNLETT | 2008年 / 17期
关键词：
ring contractions; quinones; lapachones; iodine; hydrogen peroxide;
D O I：
10.1055/s-0028-1083519
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new procedure for ring contraction from 1,2-quinones using aqueous H2O2 (30%) and catalytic amount of I-2 in acetonitrile is reported.
引用
收藏
页码：2625 / 2628
页数：4
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