Interconnected network of ultrafine MnO2 nanowires on carbon cloth with weed-like morphology for high-performance supercapacitor electrodes

被引:56
|
作者
Xu, Zhihui [1 ]
Sun, Shishuai [1 ]
Cui, Wen [2 ]
Lv, Jiang [1 ]
Geng, Yaohui [1 ]
Li, Hui [1 ]
Deng, Jiachun [1 ]
机构
[1] Tianjin Univ Technol, Coll Sci, Tianjin 300384, Peoples R China
[2] Tianjin Normal Univ, Coll Phys & Mat Sci, Tianjin 300387, Peoples R China
基金
中国国家自然科学基金;
关键词
MnO2; Supercapacitor; Electrode; Nanowire; Ultrafine structure; FACILE SYNTHESIS; MANGANESE OXIDE; NANORODS; DELTA-MNO2; NANOFIBERS; ARRAYS; SHEETS; FILM;
D O I
10.1016/j.electacta.2018.02.138
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A binder-free electrode of ultrafine MnO2 nanowires grown on the carbon cloth (CC) were fabricated by simple hydrothermal method, exhibiting the interconnected network with weed-like morphological feature. The unique pore structure has a large interface surface area, and allows rapid electrolyte diffusion through its hollow/open framework and fast electron transfer though the carbon skeleton. As an electrode for supercapacitors, the ultrafine MnO2 nanowires grown on the CC (ultrafine MnO2 nanowires@CC) exhibit a high specific capacitance (1174.3 F g(-1) at the moderate current density of 2 A g(-1)), excellent rate property (stabilize at 927 F g(-1) as the current density increases to 40 A g(-1)), and good cycling stability (a negligible 0.1% decay in specific capacitances after 10,000 cycles). (c) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:340 / 346
页数:7
相关论文
共 50 条
  • [1] MnO2 nanowires-decorated carbon fiber cloth as electrodes for aqueous asymmetric supercapacitor
    Hong, Congcong
    Wang, Xing
    Yu, Houlin
    Wu, Huaping
    Wang, Jianshan
    Liu, Aiping
    FUNCTIONAL MATERIALS LETTERS, 2018, 11 (02)
  • [2] MnO2 nanoflakes/hierarchical porous carbon nanocomposites for high-performance supercapacitor electrodes
    Li, Huailong
    Jiang, Lixue
    Cheng, Qilin
    He, Ying
    Pavlinek, Vladimir
    Saha, Petr
    Li, Chunzhong
    ELECTROCHIMICA ACTA, 2015, 164 : 252 - 259
  • [3] Ultrafine MnO2 nanowires grown on RGO-coated carbon cloth as a binder-free and flexible supercapacitor electrode with high performance
    Xu, Zhihui
    Sun, Shishuai
    Cui, Wen
    Yu, Dan
    Deng, Jiachun
    RSC ADVANCES, 2018, 8 (67): : 38631 - 38640
  • [4] MnO2/polyaniline hybrid nanostructures on carbon cloth for supercapacitor electrodes
    He, Ying
    Du, Shuangshuang
    Li, Huailong
    Cheng, Qilin
    Pavlinek, Vladimir
    Saha, Petr
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2016, 20 (05) : 1459 - 1467
  • [5] MnO2/polyaniline hybrid nanostructures on carbon cloth for supercapacitor electrodes
    Ying He
    Shuangshuang Du
    Huailong Li
    Qilin Cheng
    Vladimir Pavlinek
    Petr Saha
    Journal of Solid State Electrochemistry, 2016, 20 : 1459 - 1467
  • [6] Flower-like MnO2 decorated activated multihole carbon as high-performance asymmetric supercapacitor electrodes
    Zhu, Shijin
    Cen, Wanglai
    Hao, Longlong
    Ma, Junjun
    Yu, Liang
    Zheng, Huaili
    Zhang, Yuxin
    MATERIALS LETTERS, 2014, 135 : 11 - 14
  • [7] MnO2/Porous Carbon Nanotube/MnO2 Nanocomposites for High-Performance Supercapacitor
    Wang, Jiahao
    Guo, Xihong
    Cui, Rongli
    Huang, Huan
    Liu, Bing
    Li, Ying
    Wang, Dan
    Zhao, Dangui
    Dong, Jinquan
    Li, Shucun
    Sun, Baoyun
    ACS APPLIED NANO MATERIALS, 2020, 3 (11) : 11152 - 11159
  • [8] Freestanding MnO2 nanoflakes/porous carbon nanofibers for high-performance flexible supercapacitor electrodes
    Zhou, Dan
    Lin, Huiming
    Zhang, Feng
    Niu, Hao
    Cui, Liru
    Wang, Qian
    Qu, Fengyu
    ELECTROCHIMICA ACTA, 2015, 161 : 427 - 435
  • [9] MnO2 decorated on carbon sphere intercalated graphene film for high-performance supercapacitor electrodes
    Liu, Yu
    Cai, Xiaoyu
    Luo, Bifu
    Yan, Ming
    Jiang, Jinhui
    Shi, Weidong
    CARBON, 2016, 107 : 426 - 432
  • [10] Interconnected Network of MnO2 Nanowires with a "Cocoonlike" Morphology: Redox Couple-Mediated Performance Enhancement in Symmetric Aqueous Supercapacitor
    Maiti, Sandipan
    Pramanik, Atin
    Mahanty, Sourindra
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (13) : 10754 - 10762