Visible-light photoredox-mediated oxidation of N-methyl tertiaryamines under catalyst free conditions: Direct synthesis of methylene-bridged bis-1,3-dicarbonyl compounds

被引：12
|
作者：
Dai, Xiao-Jun [1 ]
Xu, Xiao-Liang [1 ]
Cheng, Dong-Ping [2 ]
Li, Xiao-Nian [1 ]
机构：
[1] Zhejiang Univ Technol, Inst Ind Catalysis, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China
[2] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2014年 / 25卷 / 04期
关键词：
Photochemistry; Oxidation; Aliphatic tertiaryamine; Catalyst free; ORGANIC-SYNTHESIS; AEROBIC OXIDATION; PHOTOCATALYSIS; ALKENES; FUNCTIONALIZATION; CYCLOADDITIONS; DERIVATIVES; COMPLEXES; ARYLATION; RADICALS;
D O I：
10.1016/j.cclet.2014.01.021
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mediated by visible light-induced photoredox catalysis and free of other catalysts, a new and efficient synthesis of methylene-bridged bis-1,3-dicarbonyl derivatives has been developed. A variety of N-methyl tertiaryamines and 1,3-dicarbonyl compounds were investigated in this reaction. (C) 2014 Xiao-Liang Xu and Xiao-Nian Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：545 / 548
页数：4
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