Visible-light photoredox-mediated oxidation of N-methyl tertiaryamines under catalyst free conditions:Direct synthesis of methylene-bridged bis-1,3-dicarbonyl compounds

被引：0
|
作者：
Xiao-Jun Dai [1 ]
Xiao-Liang Xu [1 ]
Dong-Ping Cheng [2 ]
Xiao-Nian Li [1 ]
机构：
[1] Institute of Industrial Catalysis,College of Chemical Engineering and Materials Science,Zhejiang University of Technology
[2] College of Pharmaceutical Science,Zhejiang University of Technology
来源：
ChineseChemicalLetters | 2014年 / 25卷 / 04期
关键词：
Photochemistry; Oxidation; Aliphatic tertiaryamine; Catalyst free;
D O I：
暂无
中图分类号：
O621.251 [];
学科分类号：
070303 ; 081704 ;
摘要：
Mediated by visible light-induced photoredox catalysis and free of other catalysts,a new and efficient synthesis of methylene-bridged bis-l,3-dicarbonyl derivatives has been developed.A variety of N-methyl tertiaryamines and 1,3-dicarbonyl compounds were investigated in this reaction.
引用
收藏
页码：545 / 548
页数：4
相关论文
共 9 条
  • [1] Visible-light photoredox-mediated oxidation of N-methyl tertiaryamines under catalyst free conditions: Direct synthesis of methylene-bridged bis-1,3-dicarbonyl compounds
    Dai, Xiao-Jun
    Xu, Xiao-Liang
    Cheng, Dong-Ping
    Li, Xiao-Nian
    CHINESE CHEMICAL LETTERS, 2014, 25 (04) : 545 - 548
  • [2] Aerobic Oxidation of a Tertiary Aliphatic Amine Under Visible-Light Photocatalysis: Facile Synthesis of Methylene-Bridged Bis-1,3-dicarbonyl Compounds
    Yoo, Woo-Jin
    Tanoue, Arata
    Kobayashi, Shu
    CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (12) : 2764 - 2767
  • [3] Synthesis of Methylene-Bridged Bis-1,3-dicarbonyl Compounds under Aerobic Condition
    Guo, Shengmei
    Gong, Jiuhan
    Lu, Lin
    Zhu, Zheng
    Cai, Hu
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2015, 35 (06) : 1348 - 1352
  • [4] Iron-Catalyzed Selective Oxidation of N-Methyl Amines: Highly Efficient Synthesis of Methylene-Bridged bis-1,3-Dicarbonyl Compounds
    Li, Haijun
    He, Zhiheng
    Guo, Xingwei
    Li, Wenjuan
    Zhao, Xuhui
    Li, Zhiping
    ORGANIC LETTERS, 2009, 11 (18) : 4176 - 4179
  • [5] Iodine-Catalyzed C-N Cleavage of Tertiary Amines: Synthesis of Methylene-Bridged Bis-1,3-dicarbonyl Compounds
    Lu, Lin
    Guo, Shengmei
    Xiong, Qiheng
    Liu, Shengyi
    Li, Xiang
    Cai, Hu
    SYNTHESIS-STUTTGART, 2014, 46 (18): : 2445 - 2450
  • [6] Gold/copper-catalyzed activation of the aci-form of nitromethane in the synthesis of methylene-bridged bis-1,3-dicarbonyl compounds
    Balamurugan, Rengarajan
    Manojveer, Seetharaman
    CHEMICAL COMMUNICATIONS, 2011, 47 (39) : 11143 - 11145
  • [7] Metal-free synthesis of methylene-bridged bis-1,3-dicarbonyl compounds via oxidative C-C bond cleavage of tertiary aliphatic amines
    Xing, Li-Juan
    Wang, Xi-Mei
    Li, Hong-Ying
    Zhou, Wen
    Kang, Ning
    Wang, Peng
    Wang, Bin
    RSC ADVANCES, 2014, 4 (51): : 26783 - 26786
  • [8] Functionalization of aliphatic tertiary amines mediated by hexachloroethane/cat. copper: synthesis of propargylic amines and methylene-bridged bis-1,3-dicarbonyl derivatives
    Xu, Xiaoliang
    Ge, Zhichuang
    Cheng, Dongping
    Li, Xiaonian
    ARKIVOC, 2012, : 107 - 118
  • [9] Oxidative C(Sp3)-H activation and C-N cleavage of N-methyl amines under transition-metal-free condition for synthesis of methylene-bridged bis-1,3-diketones
    Wang, Xiaohu
    Wang, Yi
    Yuan, Yu
    Xing, Chun-Hui
    TETRAHEDRON, 2014, 70 (12) : 2195 - 2202
1