Tris(1,10-phenanthroline)copper(II) tricyanomethanide

被引：15
|
作者：
Potocnák, I
Pohlová, M
Wagner, C
Jäger, L
机构：
[1] Safarik Univ, Dept Inorgan Chem, Inst Chem, SK-04154 Kosice, Slovakia
[2] Univ Halle Wittenberg, Inst Inorgan Chem, D-06099 Halle An Der Saale, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词：
D O I：
10.1107/S1600536802017610
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of [Cu(C12H8N2)(3)][C(CN)(3)](2) is composed of discrete [Cu(phen)(3)](2+) cations (phen is 1,10-phenanthroline) and [C(CN)(3)](-) anions. The Cu-II atom is octahedrally coordinated by the three phen ligands. As a consequence of the Jahn-Teller effect, the two axial Cu-N bonds of 2.219 (3) and 2.238 (3) Angstrom are longer than the equatorial Cu-N bonds, which are in trans positions, paired in two couples of almost equal distance [2.066 (3)/2.050 (3) and 2.121 (3)/2.121 (3) Angstrom].
引用
收藏
页码：M595 / M596
页数：2
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