A study on thermal behavior of uncalcined Ca(H2PO4)2•.H2O and CaCO3 mixtures

被引:12
|
作者
Hsu, CK [1 ]
机构
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, Taipei, Taiwan
关键词
uncalcined Ca(H2PO4)(2)center dot.H2O and CaCO3 mixtures; DTA; TG; dehydration; decomposition; non-isothermal DTA kinetics;
D O I
10.1016/S0040-6031(02)00096-5
中图分类号
O414.1 [热力学];
学科分类号
摘要
Biphase composites of hydroxyapatite (HA) and P-tricalcium phosphate, (TCP) with various phase compositions have been obtained by controlling the molar ratio of Ca(HPO4).2H(2)O and CaCO3 at an appropriate value between 1.5 and 2.0. In this work, biphase composites of HA and beta-TCP with various phase compositions were prepared from the uncalcined Ca(H2PO4)(2).H2O and CaCO3 mixtures. The thermal properties of uncalcined raw materials were investigated using DTA/DSC/TG. The kinetic parameters of dehydration and decomposition for uncalcined Ca(H2PO4)(2).H2O/CaCO3 mixtures were also evaluated by non-isothermal differential thermal analysis (DTA) techniques. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:157 / 161
页数:5
相关论文
共 50 条
  • [41] Kinetic study on the thermal dehydration of CaCO3•H2O by the master plots method
    Tang Wanjun
    Chen Donghua
    Wang Cunxin
    AICHE JOURNAL, 2006, 52 (06) : 2211 - 2216
  • [42] Precipitation of carbonated apatite in the cement system α-Ca3(PO4)2-Ca(H2PO4)2-CaCO3
    Fernandez, E
    Planell, JA
    Best, SM
    JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1999, 47 (04): : 466 - 471
  • [43] Precipitation of carbonated apatite in the cement system α- Ca3(PO4)2-Ca(H2PO4)2-CaCO3
    Fernandez, E.
    Planell, J.A.
    Best, S.M.
    Journal of Biomedical Materials Research, 1997, 47 (04): : 466 - 471
  • [44] CRYSTAL-STRUCTURE OF ANTIMONY PHOSPHATE, SBO(H2PO4).H2O
    SARNSTRAND, C
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1974, A 28 (03): : 275 - 283
  • [45] PYROLYSIS AND PRODUCTS OF PYROLYSIS OF MN(H2PO4)2.2H2O AND MG(H2PO4)2.2H2O
    SHCHEGROV, LN
    ANTRAPTSEVA, NM
    PONOMAREVA, IG
    INORGANIC MATERIALS, 1989, 25 (02) : 263 - 267
  • [46] Rapid synthesis, kinetics and thermodynamics of binary Mn0.5Ca0.5(H2PO4)2 · H2O
    Banjong Boonchom
    Chanaiporn Danvirutai
    Journal of Thermal Analysis and Calorimetry, 2009, 98 : 717 - 723
  • [47] Rapid synthesis, kinetics and thermodynamics of binary Mn0.5Ca0.5(H2PO4)2 •A H2O
    Boonchom, Banjong
    Danvirutai, Chanaiporn
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 98 (03) : 717 - 723
  • [48] Solid Liquid Phase Equilibria of (Ca(H2PO2)2 + H2O), (Ca(H2PO2)2 + CaCl2 + H2O), and (Ca(H2PO2)2 + NaH2PO2 + H2O) Systems
    Yin, Jian-nan
    Shi, Xin-ying
    Zhou, Huan
    Tang, Jing-jing
    Dai, Ya-ping
    Bai, Xiao-qin
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2017, 62 (02): : 744 - 751
  • [49] PHASE-EQUILIBRIA IN THE CA(H2PO4)2-H3PO4-H2O SYSTEM AT 25-DEGREES-C
    CHARYKOVA, MV
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1991, 64 (07): : 1247 - 1251
  • [50] Synthesis, structure, and properties of [Re2(HPO4)2(H2PO4)2(H2O)2] • 4H2O
    Shtemenko, A. V.
    Stolyarenko, V. G.
    Domasevich, K. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2007, 33 (02) : 79 - 84