Selective Hydroxylation of Adamantane and Its Derivatives

被引：17

作者：

Khusnutdinov, R. I. ^{[1
]}

Shchadneva, N. A. ^{[1
]}

Mukhametshina, L. F. ^{[1
]}

Dzhemilev, U. M. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 45卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

SATURATED-HYDROCARBONS; FUNCTIONALIZATION;

D O I：

10.1134/S1070428009080041

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general method was developed for hydroxylation into the nodal position of adamantane and its 1 and 2-substituted derivatives employing systems H2O-CBr4 (BrCCl3, CCl4) in the presence of complexes of Pd, Ni, Ru, CO, Mo, W, and Fe. The oxidants in the systems are hypochlorous (HOCl) or hypobromous (HOBr) acids generated from water and halomethanes under the reaction conditions.

引用

页码：1137 / 1142

页数：6

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