Physicochemical and catalytic properties of ruthenium nanoparticles obtained in reverse micelles

被引：1
|
作者：
Revina, A. A. [1 ,2 ]
Kuznetsov, M. A. [1 ,2 ]
Busev, S. A. [1 ]
Boeva, O. A. [2 ]
Zhavoronkova, K. N. [2 ]
机构：
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia
[2] Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia
来源：
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES | 2013年 / 49卷 / 04期
关键词：
Quercetin; Ruthenium; Optical Absorption Spectrum; Chemical Reduction; Isotopic Exchange Reaction;
D O I：
10.1134/S2070205113040126
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
We synthesized ruthenium nanoparticles in reverse-micelle solutions using radiation-chemical (under anaerobic conditions) and chemical reduction of ions (in the presence of oxygen). The optical absorption spectra recorded during nanoparticle formation differed depending on the synthesis conditions, storage, and the phenomena of adsorption/desorption on the carrier. The size of ruthenium nanoparticles was determined by atomic force microscopy (AFM) and transmission electron microscopy (TEM). Nanoparticles varied in size, shape, and size distribution according to the experimental conditions. We deposited ruthenium nanoparticles on the I"-Al2O3 carrier and studied their catalytic activity in an isotopic exchange reaction.
引用
收藏
页码：471 / 478
页数：8
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